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The lipid peroxidation process is primarily initiated by ROS (mostly OH) ( Damage to proteins ROS reacts with proteins and disrupts protein folding ( OH is the predominant ROS species that causes oxidative damage to proteins

Katsoula G, Steinberg J, Tuerlings M, Coutinho de Almeida R, Southam L, Swift D, et al

If walking causes discomfort or pain in your calves, it could be more than just muscle strain.(NIH) 8

While AA derivatives consist of a chemical blocking group added to an alpha-amino group or a modified acyl group in a specific free AA, AA analogs are developed by replacing the alpha-amino group with a non-nitrogenous group (Schwab, 1995)